Buffy The Vampire Slayer

7. Buffy/Angel/Spike, ’Buffy the Vampire Slayer’

History: Vampire Angel (David Boreanaz) and vampire slayer Buffy (Sarah Michelle Gellar) fall for one another almost immediately, but the connection between Buffy and vampire Spike (James Marsters) isn’t as immediate. One of Buffy’s "Big Bads," Spike is Buffy’s mortal enemy until a chip is implanted in his brain by the Initiative, rendering him incapable of harming humans, and he finds himself falling platinum blond head over leather booted heels for Buffy.

Outcome: Romance isn’t easy for this working woman. When Angel realizes that experiencing a moment of pure happiness with Buffy triggers a Gypsy curse that causes him to lose his soul (which leads to him tormenting Buffy until his soul is restored), they quickly realize they have no future. As for Spike, she initially resists his advances, having been burned by a vamp before, and by the time she realizes she loves him, he’s sacrificing himself to close the Hellmouth. Bummer.

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http://television.aol.com/insidetv/2009/02/05/memorable-tv-love-triangles/