Buffy The Vampire Slayer

Angel (David Boreanaz) and Buffy (Sarah Michelle Gellar) on Buffy the Vampire Slayer. From their first meeting in a darkened alley, they set my TV set ablaze. The two of them engaged one another like no one else on the series. Although, I find it hard to believe that David could not have chemistry with anyone, given his recent well matched pairing on Bones. —Liz

Buffy [Sarah Michelle Gellar] and Spike [James Marsters] on Buffy the Vampire Slayer. The characters complimented each other beautifully, and the actors played off each other perfectly whether the situation was dramatic or comedic. Plus, their onscreen connection was smokin’.

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