Buffy The Vampire Slayer

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4. Buffy and Spike in Buffy the Vampire Slayer in "Tabula Rasa": As the camera panned away from Michelle Branch singing the apropos "Goodbye to You," and snuck around the corner, viewers saw Spike and Buffy hungrily kissing. The lustful duo have had their share of fiery moments (and sweet ones like in "Once More With Feeling"), but this kiss demonstrated their mutual attraction at its most base level.

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http://blog.zap2it.com/tvgal/2008/02/pucker-up-tvs-b.html